Mohr method – determination of chlorides by titration with silver nitrate. The determination of silver or halides by the precipitation of the silver salts is known as argentometric titrations. Here titrant forms precipitate. The dispensed chloride plug is analyzed quantitatively by argentometric titration. If the titration can be performed with high enough precision, the autosampler.

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Thus far we have examined titrimetric methods based on acid—base, arggentometric, and redox reactions. Note See Table 9.

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Argentometric (silver nitrate) titrations overview

These methods are based on back titration of excess silver with standardized thiocyanate solution. Calculate pCl after the equivalence point by first calculating the concentration of excess AgNO 3 and then calculating the concentration of Cl — using the K sp for AgCl.

Before the equivalence point the titrand, Cl —is in excess. They adsorb on the AgCl surface, imparting a negative charge to the particles.

Precipitation Titrations – Chemistry LibreTexts

Argentojetric now you are familiar with our approach to calculating a titration curve. Read number of moles and mass of chlorides in the titrated sample in the output frame. What about argentometric titration?

This is relatively easy titration, with no other problems then those listed on general sources of titration errors page. The red adgentometric corresponds to the data in Table 9. All chlorides are dissolved out of the residue, and titrated. Like, we use alkalimetric titration to calculate the real concentration of table vinegar.


Methods based on precipitation of silver compounds I are called collectively argentometric methods. There are two precipitates in this analysis: Click here to review your answer to this exercise.

Finally, we complete our sketch by drawing a smooth curve that connects the three straight-line segments Figure 9. They are most often used for determination of chloride ions, but they can be used also for other halides bromide, iodide and some pseudohalides thiocyanate. Note This is the same example that we used in developing the calculations for a precipitation titration curve.

The quantitative relationship between the titrand and the titrant is determined by the stoichiometry of the titration reaction. This page was last edited on 5 Decemberat Again, the calculations are straightforward.

After the equivalence point, the titrant is in excess. The stoichiometry of the reaction requires that. By clicking “Post Your Answer”, you acknowledge that you have read our updated terms of serviceprivacy policy and cookie policyand that your continued use of the website is subject to these policies.

To perform titration we will need titrant – 0. About us Feedback Mohr method – determination of chlorides hitration titration with silver nitrate.

The sample contains 0.

The end point is found by visually examining the titration curve. As some excess of silver must be added before precipitate starts to form, if concentration of titrant is below 0. Because dichlorofluoroscein also carries a negative charge, it is repelled by the precipitate and remains argentlmetric solution where it has a greenish-yellow color.


Argentometric (silver nitrate) titrations overview

The first reagent is added qrgentometric excess and the second reagent used to back titrate the excess. To calculate chlorides solution concentration use EBAS – stoichiometry calculator. In the Mohr method, named after Karl Friedrich Mohrpotassium chromate is an indicator, giving red silver chromate after all chloride ions have reacted:.

See precipitation titration end point detection page for more detailed, quantitative discussion. Retrieved from ” https: A reaction in which the analyte and titrant form an insoluble precipitate also can serve as the basis for a titration. Our titrqtion is to sketch the titration curve quickly, using as few calculations as possible.

Mohr method – determination of chlorides by titration with silver nitrate

Past the equivalence point, excess silver I ions adsorb on the AgCl surface, imparting a positive charge. Calculate pCl at the equivalence point using the K sp for AgCl to tltration the concentration of Cl —.

A simple equation takes advantage of the fact that the sample contains only KCl and NaBr; thus.